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Direct injection spark-ignition (DISI) engines have been shown to have much higher engine-out hydrocarbon emissions (HC) than port fuel injected (PFI) engines. A major contribution to the increase in HC emissions is from the in-cylinder surface wetting that occurs as the fuel is injected. A previous study using an optical access engine and a fuel concentration probe demonstrated that the in-cylinder flow field and injection timing have a significant effect on the equivalence ratio at the spark plug. This study continues that work, by using a fast spectroscopic HC emission measurement device (Fast-Spec) to study time-resolved HC emissions from a 4-valve, centrally injected, single cylinder DISI engine. Three flow fields are studied: tumble, reverse tumble and stock. The tumble and reverse tumble flow fields are achieved using shrouded valves. Both early and late start of injection (SOI) timings are investigated.

A 1998 Toyota Corona passenger car with a direct injection spark ignition (DISI) engine was tested at constant engine speed (2000 rpm) over a range of loads. Engine-out and tailpipe emissions of gas phase species were measured each second. This allowed examination of the engine-out emissions for late and early injection. Regeneration of the lean NOx trap/catalyst was also examined, as was the efficiency of NOx reduction. NOx stored in the trap/catalyst is released at the leading edge of regenerations, such that the tailpipe NOx is higher than the engine-out NOx for a brief period. The efficiency of NOx reduction was <50% for the lowest loads examined. As the load increased, the efficiency of NOx reduction decreased to near 0% due to excessive catalyst temperatures. Loads sufficiently high to require a rich mixture produce high NOx reduction efficiencies, but in this case the NOx reduction occurs via the three-way catalysts on this vehicle.

A 1998 Toyota Corona passenger car with a direct injection spark ignition (DISI) engine was tested via a variety of driving cycles using California Phase 2 reformulated gasoline. A comparable PFI vehicle was also evaluated. The standard driving cycles examined were the Federal Test Procedure (FTP), Highway Fuel Economy Test, US06, simulated SC03, Japanese 10-15, New York City Cycle, and European ECE+EDU. Engine-out and tailpipe emissions of gas phase species were measured each second. Hydrocarbon speciations were performed for each phase of the FTP for both the engine-out and tailpipe emissions. Tailpipe particulate mass emissions were also measured. The results are analyzed to identify the emissions challenges facing the DISI engine and the factors that contribute to the particulates, NOx, and hydrocarbon emissions problems of the DISI engine.

The mixture preparation process was investigated in a direct-injected, 4-valve, SI engine under motored conditions. The engine had a transparent cylinder liner that allowed the fuel spray to be imaged using laser sheet Mie scattering. A fiber optic probe was used to measure the vapor phase fuel concentration history at the spark plug location between the two intake valves. The fuel injector was located on the cylinder axis. Two flow fields were examined; the stock configuration (tumble index 1.4) and a high tumble (tumble index 3.4) case created using shrouded intake valves. The fuel spray was visualized with the engine motored at 750 and 1500 RPM. Start of injection timings of 90°, 180° and 270° after TDC of intake were examined. The imaging showed that the fuel jet is greatly distorted for the high tumble condition, particularly at higher engine speeds. The tumble was large enough to cause significant cylinder wall wetting under the exhaust valves for some conditions.

The University of Texas Ethanol Vehicle Challenge team focused upon cold start/driveability, fuel economy, and emissions reduction for our 1999 Ethanol Vehicle Challenge entry. We replaced or coated all fuel system components that were not ethanol compatible. We used the stock PCM for all control functions except control of a novel cold-start system our team designed. The primary modifications for improved emissions control involved ceramic coating of the exhaust manifolds, use of close-coupled ethanol-specific catalysts, increased EGR for the operating conditions of the five longest cruises on the FTP, and our cold-start system that eliminates the need to overfuel the engine at the beginning of the FTP. This EGR control scheme should also benefit urban fuel economy. Additionally, we eliminated EGR at high load to improve power density.

Southwest Research Institute has developed a passive, flow-through, membrane which separates carbon dioxide (CO2) from other exhaust gas species. Stoichiometric exhaust gas for 0% ethanol fuels contain approximately 14% CO2 by concentration. The membrane consists of a ceramic substrate impregnated with lithium zirconate (Li2ZrO3). In the presence of temperatures of 400-600 °C the CO2 reacts with lithium zirconate to form lithium carbonate (Li2CO3). The new compound moves from the inner surface of the membrane via partial pressure gradient to the outer wall of the membrane and desorbs into a low concentration CO2 environment, e.g. atmospheric air with 400 ppm CO2. SwRI has tested the membrane under engine-like conditions, comparable to 2000 rpm 10 bar BMEP operation, on a standalone burner rig (ECTO-lab burner). On the SwRI ECTO-lab burner rig temperature, flow-rate and exhaust gas products can be independently varied.

An On-Board Distillation System (OBDS) was developed to extract, from gasoline, a highly volatile crank fuel that allows the reduction of startup fuel enrichment and significant spark retard during cold starts and warm-up. This OBDS was installed on a 2001 Lincoln Navigator to explore the emissions reductions possible on a large vehicle with a large-displacement engine. The fuel and spark calibration of the PCM were modified to exploit the benefits of the OBDS startup fuel. Three series of tests were performed: (1) measurement of the OBDS fuel composition and distillation curve per ASTM D86, (2) measurement of real-time cold start (20 °C) tailpipe hydrocarbon emissions for the first 20 seconds of engine operation, and (3) FTP drive cycles at 20 °C with engine-out and tailpipe emissions of gas-phase species measured each second. Baseline tests were performed using stock PCM calibrations and certification gasoline.